Qualitative analysis of edible oil mixture for omega-3 content using terahertz time-domain spectroscopy

Abstract

The utility of terahertz time-domain spectroscopy (THz-TDS) for the qualitative and quantitative analysis of edible oils remains underexplored. Therefore, we aimed to characterize an edible oil mixture consisting of perilla, soybean, and corn oils using THz-TDS spectroscopy and compare the findings with those from Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance (1H NMR) spectroscopy. THz-TDS was used to obtain complex optical constants such as power absorption and refractive index of oils in the range of 0.2-2.0 THz. Perilla oil mixtures were quantitatively analyzed using complex dielectric constants in the THz frequency region. We characterized the double bond structure of omega-3 in perilla oil using THz-TDS. Furthermore, we used reflection-mode THz-TDS imaging to demonstrate its application as a non-destructive authenticity test for bottled edible oil.